Sunday, April 19, 2015

Description of polymer system (physical / chemical properties) // End use of polyester

Polymer system:
The polyester is linear is linear and is usually based on polyethylene terephthalate. The degree of polymerization range from about 115 to 140 resulting in  a polymer length of about 120 mm to 150 nm with a thickness of about of 0.6 nm.
The important chemical group in the polyester is the methylene groups (-CH2-) the slightly polar carbonyl groups  (-Co) -,and the ester groups (-OCO-)
dry polymer system

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Physical properties:
 1.  Tenacity:
Polyester filaments and staple fibers are strong to very strong because of their extremely crystalline polymer system.
               
               High tenacity filament 7-8 gm/den
                Normal tenacity filaments 4.5-5.0”
 2. Hygroscopic:
 Polymer filaments and staple fibers are hydrophobic.  The lack of polarity and the extremely          crystalline structure of polyester resist the entry of water molecules into the polymer system.    MR% _0-0.4%

Chemical properties:
1. Effect of acid:
    The ester groups of the polyester polymers are resistant to acid hydrolysis. This resistance is further enhanced by the extreme crystallinity of the polyester polymer system.

2.  Effect of alkali: Sensitive to alkali.

3.  Effect of bleaches:
Normally polyester textile mlts do not need to be bleached. If bleached is required this is achievely by using hypo chloride bleaching.

4. Dry ability:
It is very difficult for dye molecules to penetrate the extremely crystalline polymer system of polyester fiber.

5. Biological agents: Resistance for months, mildews, fungus.

6.  Flammability: burn slowly.

End use of polyester:
  •        Apparel use:  men /women, children wear, tropical setting , blending with cotton, wool, acrylic, nylon etc.
  •        Domestic use: floor covering, carpet etc.
  •        Industrical use:High tenacity  PET  for tire coards, v-ropes, sail cloth, conveyor belts, paper making.

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